Surface segregation and stress relaxation in MOVPE of InGaN-based structures

STREEM-InGaN is a specialized software tool for modeling the characteristics of (0001) III-Nitride device heterostructures grown by MOCVD from conventional metal-organic precursors (TMIn, TMGa/TEGa, TMAl) and ammonia, diluted in H2/N2carrier gases. STREEM-InGaN focuses on an InGaN-based active region which implies a sequence of quantum wells and barriers as well as other stages in-between. Layers grown prior to and after the active region can be added into the simulations as well.

The software is aimed at understanding and control of the structure properties by adjusting the process recipe. In particular, the following issues can be addressed:

  • influence of the process parameters on indium incorporation into the quantum wells;
  • predictions of the actual composition profile in the active region of the heterostructure, including delayed indium incorporation into the QWs and indium tails in the cap layers or barriers. Due to indium surface segregation, the actual composition profile normally deviates from the nominal one built up from the steady-state solutions obtained for every individual epilayer at the respective growth conditions;
  • consistent computations of indium incorporation and elastic energy allows the users to follow and adjust the strain distribution in the active region by both modifying the operating parameters for the particular layers and adding strain-relief layers underneath the quantum wells. The actual composition and strain profiles determine the distribution of the polarization charges in the structure that can be accounted for in subsequent modeling of device operation with the SiLENSe software
  • stress relaxation via formation of V-shaped dislocation half-loops, annihilation of the threading dislocations, and evolution of the strain, threading dislocation density, and indium composition profile can be studied with the STREEM-InGaN software, depending on the particular parameters in the recipe.

As a result of the modeling, the user can analyze such characteristics as the growth rate and composition profile across the heterostructure and the distributions of strain and dislocation density. By adjusting the recipe parameters, including temperature, pressure, flow rates of the precursors and carrier gases, as well as the sequence and durations of the particular stages of the process, the user can follow the respective changes in the above characteristics and establish correlations between the recipe and properties of the heterostructure.

Indium content distribution in QW, Segal et al.(*), presented at IWN-2014, August 24-29, Wroclaw, Poland (2014)

 

Example 1: Effect of InGaN underlayers

Experiment: D.M. Van Den Broeck et al., Appl. Phys. Lett. 105 (2014) 031107.The use of InGaN underlayers (UL) and InGaN/GaN superlattices is now actively exploited during the growth of III-Nitride LED structures for strain balancing in the active regions of heterostructures. Addition an InGaN layer under the MQW stack was shown to improve the efficiency of the MQWs.

This example considers the growth of so-called strain balanced multiple quantum well (SBMQW) structures consisting of ten InxGa1-xN(4nm)/GaN(4nm) periods grown on 180 nm thick InyGa1-yN UL for x>y. The SBMQW active region implies that x=2y, if the wells and barriers have the same thickness.

InxGa1-xN/GaN MQW structures with x=16% and x=22% grown on InyGa1-yN underlayers with y=8% and y=11%, respectively, are compared to the conventional structures without UL. The modeling predicts full relaxation (in agreement with the experimental findings) of 180 nm thick underlayers, which allows the subsequent growth of a ten period MQW structure with about the same indium composition profile across the quantum wells and no additional stress relaxation. In contrast, stress relaxation after several starting QWs, formation of new dislocations in the active region, and changes in the In content distribution in the subsequent QWs are predicted for the structures without UL, as demonstrated in Fig. 2 (a-b) for the active region of the structures with different indium content.

The results agree with the experimental data by Van Den Broeck et al.: a red shift in PL emission spectra is observed for the 10 period conventional MQW structure, compared to the 2 period one, while there is no apparent shift in the PL spectra when comparing the 2 and 10 period SBMQW. This indicates that the SBMQWs are lattice matched to the InyGa1-yN template regardless the number of periods grown.

Schematic view of the structure with (a) and without (b) strain balancing underlayer. Appl. Phys. Lett. 105, 031107 (2014); https://doi.org/10.1063/1.4890738

Comparison of the composition profiles in the active region of the lnxGa1-xN/GaN MQW structures grown on GaN and InyGa1-yN ULs for x=0.16

Comparison of the composition profiles in the active region of the lnxGa1-xN/GaN MQW structures grown on GaN and InyGa1-yN ULs for x=0.16

Comparison of the composition profiles in the active region of the lnxGa1-xN/GaN MQW structures grown on GaN and InyGa1-yN ULs for x=0.22

Comparison of the composition profiles in the active region of the lnxGa1-xN/GaN MQW structures grown on GaN and InyGa1-yN ULs for x=0.22

 

Example 2: Adding aluminum into the barriers of MQW structures

Modeling analysis is given for the experimental data by K. Lekhal et al., Appl. Phys. Lett. 106 (2015) 142101.One of the effective techniques to improve the emitting characteristics of the InGaN/GaN heterostructures is the introduction of tensile AlGaN layers into the GaN barriers, which compensates for the compressive strain in the InGaN MQWs. Using this technique, it becomes possible to shift the peak wavelength in the green and spectral area without degradation of the heterostructure quality and with higher emission intensity. The example illustrates how this effect is reproduced with STREEM-InGaN.

The structure we considered is shown on the right, while the thicknesses of GaN and Al0.2Ga0.8N in the barriers are summarized in the table. Calculated temporal variation of the threading dislocation density at the growth surface for samples A and A2 are presented below together with the indium composition profiles.

Schematic view of the MQW structure.

Schematic view of the MQW structure, K. Lekhal et al., Appl. Phys. Lett. 106 (2015) 142101

For sample A, the modeling predicts stress relaxation and intensive generation of new dislocations without AlGaN in the barriers, so that only four QWs can be grown with no stress relaxation. Adding AlGaN into the barriers (sample A2) delays the onset of stress relaxation due to partial compensation of the compressive stress in QWs by the tensile stress in the barriers. The threading dislocation density and critical number of QWs that can be grown without stress relaxation are given in Fig. 7 as a function of the AlGaN barrier thickness. Increase of the AlGaN barrier thickness gradually suppresses mismatch stress relaxation; eventually, no relaxation is predicted for structure A3. This finding correlates with the observed increase in the integrated PL intensity when AlGaN is added into the barriers.

Structural data of the MQWs

Structural data of the MQWs, K. Lekhal et al., Appl. Phys. Lett. 106 (2015) 142101

Threading dislocation density and InN molar fraction in the active region for sample A.

Threading dislocation density and InN molar fraction in the active region for sample A

Threading dislocation density and InN molar fraction in the active region for sample A2.

Threading dislocation density and InN molar fraction in the active region for sample A2

TDD and critical number of QWs vs AlGaN barrier thickness.

TDD and critical number of QWs vs AlGaN barrier thickness

Publications

“Stress Relaxation in (0001) InGaN/GaN Heterostructures via V-Shape
Dislocation Formation” by M. E. Rudinsky, A. V. Lobanova, N. Cherkashin, A. F. Tsatsulnikov, V. V. Lundin, S. Yu. Karpov and E. V. Yakovlev, presented at ICNS-11 (2015)

“Управление профилем состава и напряжений в приборных гетеростуктурах на
основе InGaN”, А.С. Сегаль, Е.В. Яковлев, С.Ю. Карпов, М.Э. Рудинский, А.В. Лобанова, Р.А. Талалаев, 10-я Всероссийская конференция НИТРИДЫ ГАЛЛИЯ, ИНДИЯ И АЛЮМИНИЯ – СТРУКТУРЫ И ПРИБОРЫ (2015)

* “Atomic-scale composition profiles of MOCVD-grown InGaN/GaN quantum wells: Modeling and characterization” by A. Segal, E. Yakovlev, S. Karpov, M. Korytov, N. Cherkashin, J. Bassen, H.-J. Lugauer, and H. Laux, jointly with ITMO University (Russia), CEMES-CNRS (France), OSRAM Opto Semiconductors, GmbH (Germany).  Presented at IWN-2014, August 24-29, Wroclaw, Poland (2014)

“Correlations between Epitaxy Recipe, Characteristics, and Performance of Nitride Light Emitting Diode Structures” by Eugene V. Yakovlev, Alexander S. Segal, Kirill A. Bulashevich, Sergey Yu. Karpov, and Roman A. Talalaev, JJAP 52 (2013) 08JB15, DOI: 10.7567/JJAP.52.08JB15. For more on the subject see SiLENSe

“New Mechanism of Stress Relaxation in (0001) InGaN-Based Heterostructures” by A. V. Lobanova, A. L. Kolesnikova, A. E.Romanov, S. Y. Karpov, Michael E. Rudinsky and E. V. Yakovlev, presented at ICNS-10 (2013)

“Mechanism of stress relaxation in (0001) InGaN/GaN via formation of V-shaped dislocation half-loops” by A. V. LobanovaA. L. KolesnikovaA. E. RomanovS. Yu. KarpovM. E. Rudinsky, and E. V. Yakovlev, Appl. Phys. Lett. 103, 152106 (2013); https://doi.org/10.1063/1.4824835

“Indium Segregation Kinetics in MOVPE of InGaN-Based Heterostructures” by S. Yu. Karpov, R. A. Talalaev, I. Yu. Evstratov, and Yu. N. Makarov, phys. stat. sol. (a) 192, No. 2, 417–423 (2002)

“Mechanism of stress relaxation in (0001) InGaN/GaN via formation of V-shaped dislocation half-loops” by A. V. LobanovaA. L. KolesnikovaA. E. RomanovS. Yu. KarpovM. E. Rudinsky, and E. V. Yakovlev, Appl. Phys. Lett. 103, 152106 (2013); https://doi.org/10.1063/1.4824835